The web access from work is not white-list based, but does seem to do blocking in some other ways as well. There is content blocking using St. Bernard iPrism, which is black-list based. The effectiveness of this blocker seems heavily dependent on my browser however, 70% of its blocks don't work outside of IE.
There is some sort of other filtering/blocking going on at the router/network level as well I believe, because as I mentioned previously, I also cannot remote into my home PC using Windows Remote Desktop, and this service also works on other networks, even on this machine (my work PC is a laptop).